Diels-alder click reaction for the preparation of polycarbonate block copolymers

Omurtag P. S., Günay U. S., DAG A., DURMAZ H., HIZAL G., TUNCA Ü.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.51, sa.10, ss.2252-2259, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 51 Sayı: 10
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1002/pola.26608
  • Dergi Adı: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2252-2259
  • Anahtar Kelimeler: aliphatic polycarbonate (PC), anthracene terminated polycarbonate, block copolymer, click reactions, Diels-Alder click reaction, gel permeation chromatography (GPC), H NMR spectroscopy, maleimide-terminated poly(epsilon-caprolactone), maleimide-terminated poly(ethylene glycol), maleimide-terminated poly(methyl methacrylate), RING-OPENING POLYMERIZATION, CYCLIC CARBONATE, RADICAL POLYMERIZATION, POLY(ETHYLENE GLYCOL), GRAFT-COPOLYMERS, STAR POLYMERS, METAL-FREE, FUNCTIONALIZATION, CONSTRUCTION, TERPOLYMERS
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

The Diels-Alder reaction as a click reaction strategy is applied to the preparation of well-defined polycarbonate (PC)-block copolymers. A well-defined -anthracene-terminated polycarbonate (PC-anthracene) is prepared using 9-anthracene methanol as an initiator in the ring opening polymerization of benzyl 5-methyl-2-oxo-1,3-dioxane-5-carboxylate in CH2Cl2 at room temperature for 5 h. Next, a well-defined -furan protected maleimide-terminated-poly(ethylene glycol) (PEG11-MI or PEG37-MI), -poly(methyl methacrylate) (PMMA26-MI), and -poly(epsilon-caprolactone) (PCL27-MI) were clicked with the PC-anthracene at reflux temperature of toluene to yield their corresponding PC-based block copolymers (PC-b-PEG, PC-b-PMMA, and PC-b-PCL). The homopolymer precursors and their block copolymers were characterized by using the GPC, NMR and UV analysis. (c) 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013, 51, 2252-2259