Performance of Zn-Schiff Base complex catalyst in NaBH4 hydrolysis reaction

Kilinc D., Sahin Ö.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, cilt.45, sa.60, ss.34783-34792, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 45 Sayı: 60
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.ijhydene.2020.07.156
  • Dergi Adı: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Artic & Antarctic Regions, Chimica, Communication Abstracts, Compendex, Environment Index, INSPEC
  • Sayfa Sayıları: ss.34783-34792
  • Anahtar Kelimeler: Sodium borohydride, Catalyst, Schiff base, Hydrolysis, SODIUM-BOROHYDRIDE HYDROLYSIS, HYDROGEN GENERATION, H-2 GENERATION, B CATALYST, COBALT, STORAGE, FUEL, KINETICS, NICKEL, RU
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

This study presents 4,40-methylenebis(2,6-diethyl)aniline-3,5-ditertbutylsalisilaldimine-Zn complex synthesis and its using as a catalyst in sodium borohydride hydrolysis to H-2 generation. Surface morphology and structural properties of Zn-complex were investigated with XRD, FTIR, SEM, and BET analysis. The effects of different substrate concentration, effects of solution temperature, and effects of catalyst amount were studied for the hydrogen generation rate. Additionally kinetic parameters were studied. The activation energy was 22.978 kJ/mol and H-2 generation rates were calculated as 952.5 mmol H-2/g(cat). min and 614.4 mmol H-2/g(cat). min at 50 degrees C and 30 degrees C respectively for sodium borohydride hydrolysis reaction. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.