Benzylation of alcohols by using bis[acetylacetonato]copper as catalyst

Sirkecioglu O., KARLIGA B., TALINLI N.

TETRAHEDRON LETTERS, cilt.44, sa.46, ss.8483-8485, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 46
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1016/j.tetlet.2003.09.106
  • Dergi Adı: TETRAHEDRON LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.8483-8485
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

Selective O-benzylation of primary hydroxy compounds has been achieved in the presence of bis[acetylacetonato]copper with benzyl chloride. We showed that bis[acetylacetonato]copper was very efficient in promoting the benzylation of primary aliphatic alcohols versus secondary aliphatic alcohols and phenolic hydroxy groups selectively. (C) 2003 Elsevier Ltd. All rights reserved.