Synthesis and characterization of novel phthalocyanines with four 17-membered diazadithiamonooxa macrocycles


Sesalan F., Okur A.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.29, ss.1525-1537, 1999 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 29 Konu: 9
  • Basım Tarihi: 1999
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Sayfa Sayıları: ss.1525-1537

Özet

New phthalocyanines, (M = Cu, Zn, Ni) substituted with four 17-membered N2S2O macrocycles have been prepared starting from 1,5-bis(2'-aminophenylthia)-3-oxapentane (1a), which was tosylated and then subsequently reacted with 1,2-dibromo-4,5-bis(bromomethyl)benzene to form the macrocyclic structure (2a). The phthalocyanines (3) - (5) are soluble in chloroform, DMF, DMSO and pyridine.