Heteroarm H-shaped terpolymers through the combination of the Diels-Alder reaction and controlled/living radical polymerization techniques


Durmaz H., Tunca Ü., Tunca Ü., Hızal G.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.44, sa.13, ss.3947-3957, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 13
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1002/pola.21499
  • Dergi Adı: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3947-3957
  • Anahtar Kelimeler: anthracene, atom transfer radical polymerization (ATRP), Diels-Alder reaction, H-shaped polymers, maleimide, nitroxide-mediated radical polymerization, poly(ethylene oxide), poly(propylene oxide), polystyrene, poly(tert-butyl acrylate), BLOCK-COPOLYMERS, CLICK-CHEMISTRY, FUNCTIONALIZED POLYMERS, CYCLOADDITION, MALEIMIDES, ANTHRACENE, DENDRIMERS, LIGATION, ALKYNES, AZIDES
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Heteroarm H-shaped terpolymers (PS)(PtBA)-PEO-(PtBA)(PS) and (PS) (PtBA)-PPO-(PtBA)(PS) [where PS is polystyrene, PtBA is poly(tert-butyl acrylate). PEO is poly(ethylene oxide), and PPO is poly(propylene oxide)], containing PEO or PPO as a backbone and PS and PtBA as side arms, were prepared via the combination of the Diels-Alder reaction and atom transfer radical and nitroxide-mediated radical polymerization routes. Commercially available PEO or PPO containing bismaleimide end groups was reacted with a compound having an anthracene functionality, succinic acid anthracen-9-yl-methyl ester 3-(2-bromo-2-methylpropionyloxy)-2-methyl-2-[2-phenyl-2-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethoxycarbonyl]propyl ester, with a Diels-Alder reaction strategy. The obtained macroinitiator with tertiary bromide and 2,2,6,6-tetramethylpiperidin-1-oxy functional end groups was used subsequently in the atom transfer radical polymerization of tert-butyl acrylate and in the nitroxide-mediated free-radical polymerization of styrene to produce heteroarm H-shaped terpolymers with moderately low molecular weight distributions (< 1.31). The polymers were characterized with H-1 NMR, ultraviolet, get permeation chromatography, and differential scanning calorimetry. (c) 2006 Wiley Periodicals, Inc.